As with other metals, it becomes more reactive as it is more finely divided. Ultrafine iron powder is pyrophoric and potentially explosive. Explosive or violent reaction with ammonium nitrate + heat, ammonium peroxodisulfate, chloric acid, chlorine trifluoride, chloroformamidinium nitrate, bromine pentafluoride + heat (with iron powder), air + oil (with iron dust), sodium acetylide. Ignites on contact with chlorine, dinitrogen tetraoxide, liquid fluorine, hydrogen peroxide (with iron powder), nitryl fluoride + heat, peroxyformic acid, potassium perchlorate, potassium dichromate, sodium peroxide (at 240°), polystyrene + friction or spark (iron powder). Mixtures of iron dust with air + water may ignite on drying. Reduced iron reacts with water to produce explosive hydrogen gas. Catalyzes the exothermic polymerization of acetaldehyde. See also IRON COMPOUNDS, IRON DUST, and FERROUS ION.
Analytical Methods:
For occupational chemical analysis use NIOSH: Elements (ICP), 7300; Metals in Urine (ICP), 8310.
liansport Information:UN 1383/3089
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